Transformations of n-hexane and cyclohexane by barrier discharge processing in inert gases

被引：7
|
作者：
Kudryashov, SV [1 ]
Ryabov, AY [1 ]
Sirotkina, EE [1 ]
Shchegoleva, GS [1 ]
机构：
[1] Russian Acad Sci, Inst Petr Chem, Siberian Div, Tomsk 634055, Russia
来源：
HIGH ENERGY CHEMISTRY | 2001年 / 35卷 / 02期
关键词：
Alkenyl - Barrier discharges - Bicyclohexyl - Energy-consumption - Hexane vapors - Hydrocarbon molecules - N-Hexane;
D O I：
10.1023/A:1004125607204
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The conversion of n-hexane and cyclohexane by barrier discharge treatment in He, Ar, Kr, or Xe was studied. The action of a barrier discharge on n-hexane vapor primarily results in the formation of branched-chain hydrocarbons (93.48 wt %). Bicyclohexyl is the main reaction product of cyclohexane; alkyl and alkenyl substituted cyclohexanes (48.12 wt %) are also formed. Using n-hexane as an example, it was demonstrated that the energy consumption increased from 1.30 to 2.17 keV per hydrocarbon molecule converted in the following order of inert gases: He, Ar, Kr, and Xe.
引用
收藏
页码：120 / 122
页数：3
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