A novel fumed silica-supported nitrogenous platinum complex as a highly efficient catalyst for the hydrosilylation of olefins with triethoxysilane

被引：42

作者：

Li, Ji ^{[1
]}

Yang, Chunhui ^{[1
]}

Zhang, Lei ^{[1
]}

Ma, Tianlong ^{[1
]}

机构：

[1] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 09期

关键词：

Supported catalyst; Nitrogenous platinum complex; Hydrosilylation; Heterogeneous catalysis; PALLADIUM; BEHAVIOR;

D O I：

10.1016/j.jorganchem.2011.02.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel fumed silica-supported nitrogenous platinum complex was conveniently prepared from cheap gamma-aminopropyltriethoxysilane via immobilization on fumed silica in toluene, followed by a reaction with hexachloroplatinic acid. The title complex was characterized by fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). It was found that the complex is an efficient and stable catalyst for the hydrosilylation of olefins with triethoxysilane. The title platinum complex could be separated by simple filtration and reused several times without any appreciable loss in the catalytic activity. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.

引用

页码：1845 / 1849

页数：5

共 50 条

[1] MCM-41-supported mercapto platinum complex as a highly efficient catalyst for the hydrosilylation of olefins with triethoxysilane
Hu, Ronghua
Zha, Lingfang
Cai, Mingzhong
CATALYSIS COMMUNICATIONS, 2010, 11 (06) : 563 - 566
[2] Synthesis of a fumed silica-supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane
Li, Ji
Zhang, Lei
Li, Tingting
Yang, Chunhui
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2016, 191 (05) : 728 - 733
[3] Synthesis of a novel fumed silica-supported bidentate arsine rhodium complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane
Liu, Gang
Cai, Mingzhong
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 258 (1-2) : 257 - 260
[4] Silica-supported chitosan–platinum complex catalyst for hydrosilylation reactions
Jianbo Zhao
Xiaoli Sun
Bing Xie
Guoqing Wang
Shiqiu Song
Yu’An Sun
Research on Chemical Intermediates, 2009, 35 : 625 - 631
[5] Synthesis of a novel fumed silica-supported poly-4-oxa-6,7-bis(diphenylarsino)heptylsiloxane platinum complex and its catalytic behavior in the hydrosilylation of olefins with triethoxysilane
Liu, Gang
Huang, Bin
Cai, Mingzhong
REACTIVE & FUNCTIONAL POLYMERS, 2007, 67 (04) : 294 - 298
[6] Silica-supported chitosan-platinum complex catalyst for hydrosilylation reactions
Zhao, Jianbo
Sun, Xiaoli
Xie, Bing
Wang, Guoqing
Song, Shiqiu
Sun, Yu'An
RESEARCH ON CHEMICAL INTERMEDIATES, 2009, 35 (05) : 625 - 631
[7] Super-microporous silica-supported platinum catalyst for highly regioselective hydrosilylation
Hu, Wenbin
Xie, Huilin
Yue, Hangbo
Prinsen, Pepijn
Luque, Rafael
CATALYSIS COMMUNICATIONS, 2017, 97 : 51 - 55
[8] Preparation of efficient and environment-friendly silica-supported EDTA platinum catalyst and its applications in hydrosilylation of olefins and methyldichlorosilane
Li, Futing
Li, Youxin
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 420 : 254 - 263
[9] Graphite oxide-supported Karstedt catalyst for the hydrosilylation of olefins with triethoxysilane
Rao, Fuyuan
Deng, Shengjun
Chen, Chao
Zhang, Ning
CATALYSIS COMMUNICATIONS, 2014, 46 : 1 - 5
[10] A diphosphino-functionalised MCM-41-anchored platinum complex: an efficient and reusable catalyst for the hydrosilylation of olefins
Zha, Lingfang
Hao, Wenyan
Cai, Mingzhong
JOURNAL OF CHEMICAL RESEARCH, 2010, (11) : 648 - 652

← 1 2 3 4 5 →