Anticorrosion and surface evaluation of some electrodeposited Ni-Co-TiO2 nanocomposite coatings in 3.5 wt. % NaCl solutions

被引:2
作者
Mahmoud, Nady Hashem [1 ,2 ]
Negem, Mosaad Ragab [2 ]
El-Katori, Emad El-Din [3 ]
机构
[1] Fayoum Univ, Fac Sci, Chem Dept, Al Fayyum, Egypt
[2] Jouf Univ, Coll Sci & Arts Qurayate, Chem Dept, Sakakah, Saudi Arabia
[3] New Valley Univ, Fac Sci, Dept Chem, El Kharja 72511, Egypt
关键词
CORROSION-INHIBITORS; COMPOSITE COATINGS; MAGNETIC-PROPERTIES; NANO-PARTICLES; GRAIN-SIZE; NICKEL; BEHAVIOR; RESISTANCE; ALLOY; STEEL;
D O I
10.1680/jsuin.22.00017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, we are interested to provide the synthetic methodologies, chemical properties, and the corrosion performance of some Ni-xCo-yTiO(2) nanocomposite electroplated on Cu using the gluconate-cysteine bath, pointing at the classification of these materials corresponding to their stability in that simulated marine solution and recommend using these materials in such aggressive media. Electrochemical and spectroscopic measurements were employed in 3.5 wt. % NaCl electrolytes at 25 degrees C. The electrochemical properties of the applicable nanocomposite material will be studied to enhance manufacturing technology and forecast the stability of structures made from it. The produced nanocomposite coatings have been demonstrated to have high corrosion resistance in the investigated electrolyte, which is commonly utilized in hydrogen evolution reaction applications and other novel materials corrosion investigations. By characterizing the corrosion performance of the examined Ni-xCo-yTiO(2) nanocomposite coatings in 3.5 wt.% NaCl solution, the Ni-48Co-3.8TiO(2) is regarded as the most stable electrode. The results exposed that the inclusion of Co inside Ni-xCo-yTiO(2) significantly lessened the corrosion rate of the investigated composites. The surface examination revealed the presence of several materials constituents in the passive layer. DFT and Monte Carlo simulation approaches have been used to investigate and analyze the relationship between molecular structure and inhibitory effect.
引用
收藏
页码:178 / 194
页数:17
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