Anticorrosion and surface evaluation of some electrodeposited Ni-Co-TiO2 nanocomposite coatings in 3.5 wt. % NaCl solutions

被引:2
作者
Mahmoud, Nady Hashem [1 ,2 ]
Negem, Mosaad Ragab [2 ]
El-Katori, Emad El-Din [3 ]
机构
[1] Fayoum Univ, Fac Sci, Chem Dept, Al Fayyum, Egypt
[2] Jouf Univ, Coll Sci & Arts Qurayate, Chem Dept, Sakakah, Saudi Arabia
[3] New Valley Univ, Fac Sci, Dept Chem, El Kharja 72511, Egypt
关键词
CORROSION-INHIBITORS; COMPOSITE COATINGS; MAGNETIC-PROPERTIES; NANO-PARTICLES; GRAIN-SIZE; NICKEL; BEHAVIOR; RESISTANCE; ALLOY; STEEL;
D O I
10.1680/jsuin.22.00017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Herein, we are interested to provide the synthetic methodologies, chemical properties, and the corrosion performance of some Ni-xCo-yTiO(2) nanocomposite electroplated on Cu using the gluconate-cysteine bath, pointing at the classification of these materials corresponding to their stability in that simulated marine solution and recommend using these materials in such aggressive media. Electrochemical and spectroscopic measurements were employed in 3.5 wt. % NaCl electrolytes at 25 degrees C. The electrochemical properties of the applicable nanocomposite material will be studied to enhance manufacturing technology and forecast the stability of structures made from it. The produced nanocomposite coatings have been demonstrated to have high corrosion resistance in the investigated electrolyte, which is commonly utilized in hydrogen evolution reaction applications and other novel materials corrosion investigations. By characterizing the corrosion performance of the examined Ni-xCo-yTiO(2) nanocomposite coatings in 3.5 wt.% NaCl solution, the Ni-48Co-3.8TiO(2) is regarded as the most stable electrode. The results exposed that the inclusion of Co inside Ni-xCo-yTiO(2) significantly lessened the corrosion rate of the investigated composites. The surface examination revealed the presence of several materials constituents in the passive layer. DFT and Monte Carlo simulation approaches have been used to investigate and analyze the relationship between molecular structure and inhibitory effect.
引用
收藏
页码:178 / 194
页数:17
相关论文
共 49 条
  • [31] Stability of Zn–Ni–TiO2 and Zn–TiO2 nanocomposite coatings in near-neutral sulphate solutions
    A. Gomes
    I. Almeida
    T. Frade
    A. C. Tavares
    Journal of Nanoparticle Research, 2012, 14
  • [32] Effects of pulse plating parameters on the microstructure and properties of high frequency pulse electrodeposited Ni-Co/ZrO2 nanocomposite coatings
    Jiang, Yancheng
    Xu, Yunhua
    Wang, Mei
    Yao, Hanchao
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (01) : 610 - 616
  • [33] Chitosan-polyaniline-TiO2 ternary nanocomposite coating as effective anti-corrosion material for low carbon steel in 3.5 wt% NaCl solution
    Mobin, Mohammad
    Ansar, Farina
    Shoeb, Mohd
    JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 2023, 37 (22) : 3187 - 3205
  • [34] Experimental studies on wear and corrosion resistance of pulse electrodeposited Ni-TiO2 nanocomposite coatings on AISI 304 stainless steel
    Suresh, V
    Jegan, A.
    MATERIALS RESEARCH EXPRESS, 2022, 9 (12)
  • [35] Comparison on long-term corrosion performance of WC-CoCr and Al2O3-TiO2 ceramic coatings in sulphide-containing 3.5 wt% NaCl solution
    Wei, Ziyu
    Hong, Sheng
    Wei, Zheng
    Hu, Ning
    Ying, Guobing
    Wu, Yuping
    INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2022, 107
  • [36] Preparation of MoSi2-particle reinforced Ni-W alloy coatings and their anti-corrosion behavior in CO2-saturated 3.5 % NaCl solution
    Li, Hongjie
    Wen, Shaomu
    Yu, Zhiming
    Hu, Junkun
    Yan, Jing
    Ren, Xudong
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2024, 19 (08):
  • [37] Preparation of Chromium Carbide-Strengthened Ni-W Coatings by Electrodeposition and the Corresponding Anticorrosion Behavior in CO2-Saturated NaCl Solution
    Li, Hongjie
    Zhang, Weizhi
    Yuan, Xi
    Li, Puzhi
    Han, Weilei
    Huang, Hongbing
    COATINGS, 2024, 14 (11)
  • [38] INFLUENCE OF NANO-TiO2 CO-DEPOSITION ON THE MORPHOLOGY, MICROTOPOGRAPHY AND CRYSTALLINITY OF Ni/NANO-TiO2 ELECTROSYNTHESIZED NANOCOMPOSITE COATINGS
    Pavlov, A. I.
    Benea, L.
    Celis, J. -P.
    Vazquez, L.
    DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 2013, 8 (03) : 1043 - 1050
  • [39] Evaluation of TiO2 Nanoparticles Concentration and Applied Current Density Role in Determination of Microstructural, Mechanical, and Corrosion Properties of Ni-Co Alloy Coatings
    Rasooli, Ali
    Safavi, Mir Saman
    Ahmadiyeh, Somayeh
    Jalali, Akram
    PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2020, 56 (02) : 320 - 327
  • [40] Hot corrosion of surface-modified Sm2Co17 high-temperature magnet with Ni and Ni/Cr bilayer coatings in 75 wt% Na2SO4-NaCl mixture
    Bibi, Saira
    Wang, Jing-Min
    Mehmood, Tariq
    Khan, Waheed Qamar
    Jiang, Cheng-Bao
    RARE METALS, 2021, 40 (09) : 2494 - 2500