Visualizing the degradation of nerve agent simulants using functionalized Zr-based MOFs: from solution to hydrogels

被引：11

作者：

Su, Hongyan ^{[1
]}

Huang, Pengcheng ^{[1
]}

Wu, Fang-Ying ^{[1
]}

机构：

[1] Nanchang Univ, Coll Chem, Nanchang 330031, Jiangxi, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 88期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; TURN-ON; HYDROLYSIS; EFFICIENT; FACILE;

D O I：

10.1039/d1cc05199g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visual monitoring of the degradation of nerve agent simulants based on the switchable fluorescence of UiO-66-NH2 was developed. In the hydrolysis, the decomposition products perturbed the linker-to-cluster charge transfer and stimulated the fluorescence recovery. Moreover, a "soft" solid-state platform utilizing agarose hydrogels was proposed to visualize the degradation of gaseous simulants without bulk water.

引用

页码：11681 / 11684

页数：4

共 38 条

[1] Soft Mode Metal-Linker Dynamics in Carboxylate MOFs Evidenced by Variable-Temperature Infrared Spectroscopy
Andreeva, Anastasia B.
Le, Khoa N.
Chen, Lihaokun
Kellman, Michael E.
Hendon, Christopher H.
Brozek, Carl K.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (45) : 19291 - 19299
[2] Metal Organic Framework Functionalized Textiles as Protective Clothing for the Detection and Detoxification of Chemical Warfare Agents-A Review
Balasubramanian, Selva
Kulandaisamy, Arockia Jayalatha
Babu, K. Jayanth
Das, Apurba
Rayappan, John Bosco Balaguru
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2021, 60 (11) : 4218 - 4239
[3] Metal-organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents
Bobbitt, N. Scott
Mendonca, Matthew L.
Howarth, Ashlee J.
Islamoglu, Timur
Hupp, Joseph T.
Farha, Omar K.
Snurr, Randall Q.
[J]. CHEMICAL SOCIETY REVIEWS, 2017, 46 (11) : 3357 - 3385
[4] Porphyrinic Metal-Organic Framework Catalyzed Heck-Reaction: Fluorescence "Turn-On" Sensing of Cu(II) Ion
Chen, Yu-Zhen
Jiang, Hai-Long
[J]. CHEMISTRY OF MATERIALS, 2016, 28 (18) : 6698 - 6704
[5] Technological advancements for the detection of and protection against biological and chemical warfare agents
Eubanks, Lisa M.
Dickerson, Tobin J.
Janda, Kim D.
[J]. CHEMICAL SOCIETY REVIEWS, 2007, 36 (03) : 458 - 470
[6] The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, Hiroyasu
Cordova, Kyle E.
O'Keeffe, Michael
Yaghi, Omar M.
[J]. SCIENCE, 2013, 341 (6149) : 974 - +
[7] Ratiometric fluorescence detection of phosphate in human serum with a metal-organic frameworks-based nanocomposite and its immobilized agarose hydrogels
Gao, Nan
Huang, Jian
Wang, Liyuan
Feng, Jiayu
Huang, Pengcheng
Wu, Fangying
[J]. APPLIED SURFACE SCIENCE, 2018, 459 : 686 - 692
[8] Smart textiles of MOF/g-C3N4 nanospheres for the rapid detection/detoxification of chemical warfare agents
Giannakoudakis, Dimitrios A.
Hu, Yuping
Florent, Marc
Bandosz, Teresa J.
[J]. NANOSCALE HORIZONS, 2017, 2 (06) : 356 - 364
[9] Efficient removal of phosphate from acidified urine using UiO-66 metal-organic frameworks with varying functional groups
Guan, Tong
Li, Xiaodi
Fang, Wenkan
Wu, Deyi
[J]. APPLIED SURFACE SCIENCE, 2020, 501
[10] Amine-Responsive Adaptable Nanospaces: Fluorescent Porous Coordination Polymer for Molecular Recognition
Haldar, Ritesh
Matsuda, Ryotaro
Kitagawa, Susumu
George, Subi J.
Maji, Tapas Kumar
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (44) : 11772 - 11777

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