A series of metal-organic coordination polymers containing multiple chiral centers

被引:27
作者
Yang, Xiu-Li [1 ]
Xie, Ming-Hua [1 ]
Zou, Chao [1 ]
Sun, Fei-Fei [1 ]
Wu, Chuan-De [1 ,2 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Chinese Acad Sci, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源
CRYSTENGCOMM | 2011年 / 13卷 / 05期
基金
高等学校博士学科点专项科研基金;
关键词
AMINO-ACIDS; CRYSTAL-STRUCTURES; ABSOLUTE HELICITY; RATIONAL DESIGN; FRAMEWORK; H-2; SEPARATION; CONVERSION; INDUCTION; COMPLEXES;
D O I
10.1039/c0ce00633e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new trifunctional amino acid derivatives, (S-2-(pyridine-4-ylmethylamino) succinic acid (L1) and S-2-(pyridin-4-ylmethylamino)pentanedioic acid (L2)), containing carboxylate, achiral amine and pyridine groups, were used as effective bridging ligands for the synthesis of six homochiral coordination networks of [ZnL1(H2O)(2)]center dot H2O (1), [CoL1(H2O)(2)]center dot H2O (2), [ZnL2(H2O)(2)] (3), [NiL1(H2O)]center dot H2O (4), [Cd(2)L1(2)(H2O)]center dot 3H(2)O (5) and [CdL2]center dot H2O (6). Compounds 1, 2 and 3 adopt 1D polymeric linear networks, and compound 4 presents a 2D lattice framework, while compounds 5 and 6 comprise 3D networks containing small voids occupied by water molecules. The achiral amine groups within all six compounds are induced by the neighbouring chiral carbon centres into homochiral units to coordinate transition metal cations. Hydrogen bonding contacts play very important roles for the formation and stabilization of these homochiral coordination networks. The magnetic properties of 2 and 4, and the photoluminescent properties of 1, 3, 5 and 6 in solid state were investigated.
引用
收藏
页码:1570 / 1579
页数:10
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