Behaviour and distribution of arsenic in seawater and suspended particulate matter in the adjacent area of the Changjiang Estuary during summer and autumn

Water and suspended particulate matter (SPM) were collected from the Changjiang Estuary and its adjacent areas during summer (July) and autumn (October) to study the distributions and partitioning of arsenic. The dissolved arsenic (DAs) and particulate arsenic (PAs) concentration distributions were strongly affected by inputs from riverine discharge and water masses in the East China Sea, generally exhibiting a decreasing trend from inshore to offshore. The DAs concentration was higher in the surface water due to the influence of seawater stratification in summer, but it was not obvious in autumn. DAs and PAs concentrations in the estuary were significantly higher in autumn than in summer. Seasonal variations in arsenic were due to seasonal differences in riverine input (mainly the Changjiang River) and the intrusion of water masses. PAs showed a positive correlation with both SPM and turbidity. The highest PAs concentration was observed in the northern Changjiang Estuary affected by the YSCC, with higher turbidity during autumn. The higher concentration of PAs in autumn was affected by the high SPM input and resuspension of sediment. The water-particulate distribution coefficient of As in summer showed an increasing tendency with salinity, which might be caused by the decrease in the diameter of suspended particles in the open sea.