Ring-opening of cyclopropanes by "frustrated Lewis pairs"

被引：51
|
作者：
Morton, Jason G. M. [1 ]
Dureen, Meghan A. [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 47期
基金：
加拿大自然科学与工程研究理事会;
关键词：
VINYLIDENE-CYCLOPROPANES; HYDROGEN ACTIVATION; CASCADE REACTIONS; NITROUS-OXIDE; ACID; REACTIVITY; METHYLENECYCLOPROPANES; DERIVATIVES; REDUCTION; MECHANISM;
D O I：
10.1039/c0cc02862b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of phosphine/borane frustrated Lewis pairs with cyclopropanes result in the ring opening, yielding phosphonium borate products.
引用
收藏
页码：8947 / 8949
页数：3
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