Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst

被引：43

作者：

Yuan, Hangkong ^{[1
]}

Kusema, Bright T. ^{[2
]}

Yan, Zhen ^{[2
]}

Streiff, Stephane ^{[2
]}

Shi, Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] CNRS Solvay, E2P2L, UMI 3464, 3966 Jin Du Rd, Shanghai 201108, Peoples R China

来源：

RSC ADVANCES | 2019年 / 9卷 / 66期

关键词：

REDUCTIVE AMINATION; BIOMASS; AMINES; CHEMICALS; ALCOHOLS;

D O I：

10.1039/c9ra08560b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of facile protocols for the selective synthesis of biomass-derived diamine is a highly desirable pursuit in the field of heterogeneous catalysis. Herein, a simple and highly efficient bi-functional CuNiAlOx catalyst was developed for the one pot transformation of 5-(hydroxymethyl)furfural (5-HMF) into 2,5-bis(aminomethyl)furan (BAF) using a two-stage reaction process. Cu4Ni1Al4Ox was found to be the most effective catalyst for this reaction, affording BAF in 85.9% yield. Our results could promote controllable conversion and utilization of biomass resource.

引用

页码：38877 / 38881

页数：5

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