Behaviors of Pulp During Delignification in Solutions of Deep Eutectic Solvents: Degradation of Cellulose

被引：0

作者：

Jablonsky, Michal ^{[1
]}

Majova, Veronika ^{[1
]}

Skulcova, Andrea ^{[1
]}

Haz, Ales ^{[1
]}

Strizincova, Petra ^{[1
]}

Kreps, Frantisek ^{[1
]}

Burcova, Zuzana ^{[1
]}

Sladkova, Alexandra ^{[1
]}

Surina, Igor ^{[1
]}

机构：

[1] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Radlinskeho 9, Bratislava 81237, Slovakia

来源：

RENEWABLE ENERGY SOURCES 2018 | 2018年

关键词：

deep eutectic solvents; delignification; pulp; degradation; OXYGEN DELIGNIFICATION; CHOLINE CHLORIDE; ACID; KINETICS; LIGNIN;

D O I：

暂无

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this short communication, the degradation of cellulose for delignified pulp by deep eutectic solvents was evaluated. The pulp was delignified using different DES systems based on choline chloride and lactic acid (1:9), oxalic acid dehydrate (1:1), malic acid (1:1), and system alanine : lactic acid (1:9). This paper shows that cellulose degradation can be characterized in terms of the percentage degree of polymerization loss of cellulose. Among the investigated DES (Choline chloride:oxalic acid; choline chloride:malic acid; alanine:lactic acid; choline chloride:lactic acid), the most suitable seemed to be a treatment using the alanine:lactic acid system that provided a relatively low degradation of cellulose and high delignification efficiency for the removed of lignin from pulp.

引用

页码：22 / 24

页数：3

共 50 条

[21] Delignification and cellulose degradation kinetics models for high lignin content softwood Kraft pulp during flow-through oxygen delignification
Jafari, Vahid
Nieminen, Kaarlo
Sixta, Herbert
van Heiningen, Adriaan
CELLULOSE, 2015, 22 (03) : 2055 - 2066
[22] Understanding the Role of Choline Chloride in Deep Eutectic Solvents Used for Biomass Delignification
Smink, Dion
Juan, Alberto
Schuur, Boelo
Kersten, Sascha R. A.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (36) : 16348 - 16357
[23] Kinetics of delignification and cellulose degradation during kraft pulping with polysulphide and anthraquinone
Li, Z
Li, J
Kubes, GJ
JOURNAL OF PULP AND PAPER SCIENCE, 2002, 28 (07): : 234 - 239
[24] Delignification and cellulose degradation kinetics models for high lignin content softwood Kraft pulp during flow-through oxygen delignification
Vahid Jafari
Kaarlo Nieminen
Herbert Sixta
Adriaan van Heiningen
Cellulose, 2015, 22 : 2055 - 2066
[25] Effect of a trace amount of deep eutectic solvents on the structure and optical properties of cellulose nanocrystal films
Wei, Xiaoyao
Lin, Tao
Du, Hengli
Wang, Le
Yin, Xuefeng
CELLULOSE, 2022, 29 (09) : 5235 - 5249
[26] Delignification of Low-Energy Mechanical Pulp (Asplund Fibers) in a Deep Eutectic Solvent System of Choline Chloride and Lactic Acid
Perez, Alan D.
Fiskari, Juha
Schuur, Boelo
FRONTIERS IN CHEMISTRY, 2021, 9
[27] Separation of Cellulose and Lignin from Eucalyptus Wood by Liquefaction in Deep Eutectic Solvents
Bai, Youcan
Chen, Fangeng
Liu, Mingyou
BIORESOURCES, 2020, 15 (03) : 6886 - 6901
[28] Study on the Dissolution Mechanism of Cellulose by ChCl-Based Deep Eutectic Solvents
Zhang, Heng
Lang, Jinyan
Lan, Ping
Yang, Hongyan
Lu, Junliang
Wang, Zhe
MATERIALS, 2020, 13 (02)
[29] Esterification of cellulose using carboxylic acid-based deep eutectic solvents to produce high-yield cellulose nanofibers
Liu, Suling
Zhang, Qing
Gou, Shaheng
Zhang, Lili
Wang, Zhiguo
CARBOHYDRATE POLYMERS, 2021, 251
[30] Study on Catalytic Conversion of Cellulose to 5-Hydroxymethyl Furfural by Directional Degradation in Deep Eutectic Solvents
Yang, Hongyan
Lang, Jinyan
Lu, Junliang
Lan, Ping
Zhang, Heng
BIORESOURCES, 2020, 15 (02) : 3344 - 3355

← 1 2 3 4 5 →