Broadband dipolar recoupling in rotating solids: a numerical comparison of some pulse schemes

被引：41

作者：

Baldus, M ^{[1
]}

Geurts, DG ^{[1
]}

Meier, BH ^{[1
]}

机构：

[1] Univ Nijmegen, Chem Phys Lab, NSR, Ctr Mol Struct Design & Synth, NL-6525 ED Nijmegen, Netherlands

来源：

SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1998年 / 11卷 / 3-4期

关键词：

recoupling; magic angle spinning; pulse sequences; numerical simulations; polarization transfer; correlation spectroscopy;

D O I：

10.1016/S0926-2040(98)00036-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A numerical comparison of the dipolar recoupling performance of several previously published homonuclear recoupling schemes under magic angle-spinning conditions is presented. Emphasis is put on the recoupled polarization transfer in a two-spin system where the efficiency is studied as a function of resonance offsets in the presence and absence of chemical-shielding anisotropies. In addition, the effect of the rf field strength is investigated. Powder pattern line shapes are shown in the on-resonance case that reveal the distribution of dipolar couplings for each recoupling scheme. These results are compared to data computed with a purposely misset rf field strength to estimate the pulse scheme sensitivity to rf-inhomogeneity and experimental missettings. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：157 / 168

页数：12

共 28 条

[21] EXCITATION OF MULTIPLE QUANTUM TRANSITIONS UNDER MAGIC ANGLE SPINNING CONDITIONS - ADAMANTANE [J].

MEIER, BH ;

EARL, WL .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (09) :4905-4911

[22] DOUBLE-QUANTUM HOMONUCLEAR ROTARY RESONANCE - EFFICIENT DIPOLAR RECOVERY IN MAGIC-ANGLE-SPINNING NUCLEAR-MAGNETIC-RESONANCE [J].

NIELSEN, NC ;

BILDSOE, H ;

JAKOBSEN, HJ ;

LEVITT, MH .

JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (03) :1805-1812

[23] NUCLEAR RESONANCE ABSORPTION IN HYDRATED CRYSTALS - FINE STRUCTURE OF THE PROTON LINE [J].

PAKE, GE .

JOURNAL OF CHEMICAL PHYSICS, 1948, 16 (04) :327-336

[24] ROTATIONAL RESONANCE IN SOLID-STATE NMR [J].

RALEIGH, DP ;

LEVITT, MH ;

GRIFFIN, RG .

CHEMICAL PHYSICS LETTERS, 1988, 146 (1-2) :71-76

[25] COMPUTER-SIMULATIONS IN MAGNETIC-RESONANCE - AN OBJECT-ORIENTED PROGRAMMING APPROACH [J].

SMITH, SA ;

LEVANTE, TO ;

MEIER, BH ;

ERNST, RR .

JOURNAL OF MAGNETIC RESONANCE SERIES A, 1994, 106 (01) :75-105

[26] 3D N-15-C-13-C-13 chemical shift correlation spectroscopy in rotating solids [J].

Sun, BQ ;

Rienstra, CM ;

Costa, PR ;

Williamson, JR ;

Griffin, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (36) :8540-8546

[27] INTERNUCLEAR DISTANCE MEASUREMENTS IN SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE - DIPOLAR RECOUPLING VIA ROTOR SYNCHRONIZED SPIN LOCKING [J].

SUN, BQ ;

COSTA, PR ;

KOCISKO, D ;

LANSBURY, PT ;

GRIFFIN, RG .

JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (02) :702-707

[28] SYMMETRY PRINCIPLES IN THE DESIGN OF PULSE SEQUENCES FOR STRUCTURAL MEASUREMENTS IN MAGIC ANGLE SPINNING NUCLEAR-MAGNETIC-RESONANCE [J].

TYCKO, R ;

SMITH, SO .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (02) :932-943

← 1 2 3 →