Self-assembly and crystal structure of a three-dimensional copper(II) complex

被引：2
|
作者：
Zhang, Zun-Ting [1 ]
Shi, Juan
机构：
[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China
[2] Shanxi Univ Technol, Dept Chem, Hanzhong, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 14期
关键词：
chrysin; copper; hydrogen bonding; pi-pi stacking; crystal structure;
D O I：
10.1080/00958970601066711
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A copper( II) complex of a sulfonate derivative of chrysin, 5,7- bihydroxyflavone- 6- sulfonate, Cu(C15H8O7S)(3H(2)O), has been prepared. The complex was characterized by elemental analysis, spectroscopic measurements and single- crystal X- ray diffraction studies. It crystallizes in the monoclinic space group C2/c, with a = 16.036( 18), b = 6.944( 8), c = 28.03(3) angstrom, beta = 94.463(17)degrees, V = 3112( 6)angstrom(3), Z = 8. In the complex, Cu( II) is five-coordinate and all donors are oxygen atoms. Hydrogen bonds and pi-pi stacking interactions in the crystal lead to the formation of a three- dimensional supramolecular motif.
引用
收藏
页码：1485 / 1491
页数：7
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