Effect of anions on the formation of solid substitution solutions on the basis of clathrate hydrates in the tetrabutylammonium hydroxide tetrabutylammonium halide (F, Cl, Br) water system series

被引：0

作者：

Aladko, L. S. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 10期

关键词：

Solid Solution; Clathrate; Tetrabutylammonium; Solid Substitution Solution; Tetrabutylammonium Bromide;

D O I：

10.1134/S1070363207100052

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solubility isotherms for the tetrabutylammonium chloride tetrabutylammonium hydroxide water system at 17 and 20 degrees C were studied to reveal formation of two series of solid solutions on the basis of tetragonal (salt-water, 1 : 32) and cubic (1 : 28) clathrate hydrates. The nature of halide anions affects the formation of solid substitution solutions in the tetrabutylammonium hydroxide-tetrabutylammonium halide (F-, Cl-, Br-) water system series.

引用

页码：1682 / 1685

页数：4

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