Bis(indole)methane;
Benzo[a]xanthen-11-one;
Heterogeneous Lewis acid;
magnetic catalyst;
GO-based catalyst;
ONE-POT SYNTHESIS;
CHROMATOGRAPHY-FREE SYNTHESIS;
CROSS-COUPLING REACTION;
REUSABLE CATALYST;
IONIC LIQUID;
FE+3-MONTMORILLONITE K10;
REGIOSELECTIVE SYNTHESIS;
HETEROGENEOUS CATALYST;
HIGHLY EFFICIENT;
GREEN SYNTHESIS;
D O I:
10.1080/24701556.2021.1980039
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
In this study, a new and efficient magnetic composite was synthesized based on graphene oxide (GO). Initially, GO was coated with magnetite, and then Ti-(IV()) was fixed on GO-Fe3O4 via a covalent graft. The magnetic composite was characterized by FT-IR, EDS, XRD, FE-SEM, TEM, VSM and TGA techniques. It was designed as a compound with strong and recoverable catalytic properties. The prepared GO-Fe3O4-Ti-(IV) emerged to be of high catalytic activity for the synthesis of bis(indolyl)methane and benzo[a]xanthen-11-one derivatives under mild conditions. The stability and reusability of the catalyst were investigated too. All of the data proved that GO-Fe3O4-Ti-(IV) could be recycled five times without a marked loss of activity.