Expanding the Carbene C-H Insertion Toolbox

被引：6

作者：

Morton, Daniel ^{[1
]}

Blakey, Simon B. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

CHEMCATCHEM | 2015年 / 7卷 / 04期

基金：

美国国家科学基金会;

关键词：

carbenes; catalysis; CH functionalization; rhodium; ruthenium; DIAZO-COMPOUNDS; IN-SITU;

D O I：

10.1002/cctc.201402945

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Bigger toolbox: Two recent discoveries demonstrate significant advances in the controlled generation and C-H insertion chemistry of the previously inaccessible donor-donor and alkyl-alkyl classes of metallocarbenes. These discoveries lay the groundwork for broad reaction development with these versatile reactive species. EDG=Electron-donating group; EWG=Electron-withdrawing group; M=Transition metal. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：577 / 578

页数：2

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