Electron transfer, in organonickel complexes of α-diimines:: Versatile redox catalysts for C-C or C-P coupling reactions -: A review

被引：101
作者：
Klein, Axel
Budnikova, Yulia H.
Sinyashin, Oleg G.
机构：
[1] Univ Cologne, Inst Inorgan Chem, D-50939 Cologne, Germany
[2] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Inst Organ & Phys Chem, Kazan 420088, Russia
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 15期
关键词：
organonickel; alpha-diimine ligands; electrochemistry; electrocatalysis; spectroelectrochemistry; C-C-coupling reactions;
D O I：
10.1016/j.jorganchem.2007.01.021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Organonickel complexes with alpha-diimine ligands play an important role in electrocatalytic C-C or C-P cross coupling reactions. The review summarises recent insights into the reaction mechanisms of such reactions obtained by electrochemical experiments, electrosynthesis and spectroelectrochernistry (UV-vis-NIR or EPR). The (formal) oxidations states of the involved nickel species range from Ni(0) to Ni(III). (c) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：3156 / 3166
页数：11
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