Tandem photoelectrochemical and photoredox catalysis for efficient and selective aryl halides functionalization by solar energy

被引：44

作者：

Chen, Ya-Jing ^{[1
,2
]}

Lei, Tao ^{[1
,2
]}

Hu, Hui-Lan ^{[1
,2
]}

Wu, Hao-Lin ^{[1
,2
]}

Zhou, Shuai ^{[1
,2
]}

Li, Xu-Bing ^{[1
,2
]}

Chen, Bin ^{[1
,2
]}

Tung, Chen-Ho ^{[1
,2
]}

Wu, Li-Zhu ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100049, Peoples R China

来源：

MATTER | 2021年 / 4卷 / 07期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-TRANSFER; H FUNCTIONALIZATION; UNACTIVATED ALKYL; LIGHT; REDUCTION; ACTIVATION; WATER; PHOTOCATHODES; BOND; BORYLATION;

D O I：

10.1016/j.matt.2021.05.004

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Solar energy conversion is the most important chemical transformation for green and sustainable society. Represented herein is a coupled photoelectrochemical/photoredox (c-PEC/PC) strategy for efficient, selective and challenging organic transformations by sunlight. Under visible and near-infrared light irradiation, the c-PEC/PC setting obtains high reducing ability at a low applied potential, which realizes reductive functionalization of aryl halides, including late-stage functionalization of pharmaceutical molecules and scale-up reaction, in an energy-saving, high-efficient, high-selective and sacrificial agent-free way.

引用

页码：2354 / +

页数：14

共 72 条

[21] Photoelectrochemical cells [J].

Grätzel, M .

NATURE, 2001, 414 (6861) :338-344

[22] Boundaries of Anion/Naphthalenediimide Interactions: From Anion-π Interactions to Anion-Induced Charge-Transfer and Electron-Transfer Phenomena [J].

Guha, Samit ;

Goodson, Flynt S. ;

Corson, Lucas J. ;

Saha, Sourav .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (33) :13679-13691

[23] Interfacial Photoelectrochemical Catalysis: Solar-Induced Green Synthesis of Organic Molecules [J].

Hardwick, Tomas ;

Qurashi, Ahsanulhaq ;

Shirinfar, Bahareh ;

Ahmed, Nisar .

CHEMSUSCHEM, 2020, 13 (08) :1967-1973

[24] Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting [J].

Hisatomi, Takashi ;

Kubota, Jun ;

Domen, Kazunari .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7520-7535

[25] Electrochemical C-H/N-H Functionalization for the Synthesis of Highly Functionalized (Aza)indoles [J].

Hou, Zhong-Wei ;

Mao, Zhong-Yi ;

Zhao, Huai-Bo ;

Melcamu, Yared Yohannes ;

Lu, Xin ;

Song, Jinshuai ;

Xu, Hai-Chao .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (32) :9168-9172

[26] Continuous-Flow Electrosynthesis of Benzofused S-Heterocycles by Dehydrogenative C-S Cross-Coupling [J].

Huang, Chong ;

Qian, Xiang-Yang ;

Xu, Hai-Chao .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (20) :6650-6653

[27] Electrophotocatalysis with a Trisaminocyclopropenium Radical Dication [J].

Huang, He ;

Strater, Zack M. ;

Rauch, Michael ;

Shee, James ;

Sisto, Thomas J. ;

Nuckolls, Colin ;

Lambert, Tristan H. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (38) :13318-13322

[28] Selective CO production by Au coupled ZnTe/ZnO in the photoelectrochemical CO2 reduction system [J].

Jang, Youn Jeong ;

Jang, Ji-Wook ;

Lee, Jaehyuk ;

Kim, Ju Hun ;

Kumagai, Hiromu ;

Lee, Jinwoo ;

Minegishi, Tsutomu ;

Kubota, Jun ;

Domen, Kazunari ;

Lee, Jae Sung .

ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (12) :3597-3604

[29] O-H hydrogen bonding promotes H-atom transfer from α C-H bonds for C-alkylation of alcohols [J].

Jeffrey, Jenna L. ;

Terrett, Jack A. ;

MacMillan, David W. C. .

SCIENCE, 2015, 349 (6255) :1532-1536

[30] Hydrodehalogenation of Aryl Halides through Direct Electrolysis [J].

Ke, Jie ;

Wang, Hongling ;

Zhou, Liejin ;

Mou, Chengli ;

Zhang, Jingjie ;

Pan, Lutai ;

Chi, Yonggui Robin .

CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (28) :6911-6914

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