Tandem photoelectrochemical and photoredox catalysis for efficient and selective aryl halides functionalization by solar energy

被引：44

作者：

Chen, Ya-Jing ^{[1
,2
]}

Lei, Tao ^{[1
,2
]}

Hu, Hui-Lan ^{[1
,2
]}

Wu, Hao-Lin ^{[1
,2
]}

Zhou, Shuai ^{[1
,2
]}

Li, Xu-Bing ^{[1
,2
]}

Chen, Bin ^{[1
,2
]}

Tung, Chen-Ho ^{[1
,2
]}

Wu, Li-Zhu ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100049, Peoples R China

来源：

MATTER | 2021年 / 4卷 / 07期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-TRANSFER; H FUNCTIONALIZATION; UNACTIVATED ALKYL; LIGHT; REDUCTION; ACTIVATION; WATER; PHOTOCATHODES; BOND; BORYLATION;

D O I：

10.1016/j.matt.2021.05.004

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Solar energy conversion is the most important chemical transformation for green and sustainable society. Represented herein is a coupled photoelectrochemical/photoredox (c-PEC/PC) strategy for efficient, selective and challenging organic transformations by sunlight. Under visible and near-infrared light irradiation, the c-PEC/PC setting obtains high reducing ability at a low applied potential, which realizes reductive functionalization of aryl halides, including late-stage functionalization of pharmaceutical molecules and scale-up reaction, in an energy-saving, high-efficient, high-selective and sacrificial agent-free way.

引用

页码：2354 / +

页数：14

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