Structural Effects on the Electronic Properties of Extended Fused-Ring Thieno[3,4-b]pyrazine Analogues

被引：44

作者：

Nietfeld, Jon P. ^{[1
]}

Schwiderski, Ryan L. ^{[1
]}

Gonnella, Thomas P. ^{[2
]}

Rasmussen, Seth C. ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem & Biochem, Fargo, ND 58108 USA

[2] Mayville State Univ, Div Sci & Math, Mayville, ND 58257 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 15期

基金：

美国国家科学基金会;

关键词：

LOW-BAND-GAP; NARROW-BANDGAP; RAMAN-SPECTRA; SOLAR-CELLS; POLYMERS; POLYMERIZATION; COPOLYMER; GREEN; POLY(THIOPHENES); DONOR;

D O I：

10.1021/jo200850w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterization of the extended thieno[3,4-b]pyrazine analogues acenaphtho[1,2-b]thieno[3,4-e]pyrazine (3a), 3,4-dibromoacenaphtho[1,2-b]thieno[3,4-e]pyrazine (3b), 3-octylacenaphtho[1,2-b]thieno[3,4-e]pyrazine (3c), dibenzo[f,h]thieno[3,4-b]quinoxaline (4), and thieno[3',4':5,6]pyrazino[2,3-f][1,10]phenanthroline (5) are reported. Comparison of structural, electrochemical, and photophysical properties to those of simple thieno[3,4-b]pyrazines are provided in order to provide structure-function relationships within this series of compounds.

引用

页码：6383 / 6388

页数：6

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