Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

被引：55

作者：

Ahuja, Ritu ^{[1
]}

Kundu, Sabuj ^{[1
]}

Goldman, Alan S. ^{[1
]}

Brookhart, Maurice ^{[2
]}

Vicente, Brian C. ^{[3
]}

Scott, Susannah L. ^{[3
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

[2] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

[3] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 02期

关键词：

D O I：

10.1039/b712197k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tandem dehydrogenation-olefin-metathesis catalyst systems, comprising a pincer-ligated iridium-based alkane dehydrogenation catalyst and a molybdenum-based olefin-metathesis catalyst, are reported to effect the metathesis-cyclooligomerization of cyclooctane and cyclodecane to give cycloalkanes with various carbon numbers, predominantly multiples of the substrate carbon number, and polymers.

引用

页码：253 / 255

页数：3

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