Bicyclic guanidine-catalyzed enantioselective phospha-Michael reaction:: synthesis of chiral β-aminophosphine oxides and β-aminophosphines

被引：109

作者：

Fu, Xiao ^{[1
]}

Jiang, Zhiyong ^{[1
]}

Tan, Choon-Hong ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 47期

关键词：

D O I：

10.1039/b713151h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral bicyclic guanidine has been found to catalyze the phospha-Michael reactions of diaryl phosphine oxide to nitroalkenes with high enantioselectivities, offering a direct methodology to prepare chiral beta-aminophosphine oxides and beta-aminophosphines.

引用

页码：5058 / 5060

页数：3

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