Double loading of ZnCl2 by polytopic ligands which co-extract Zn2+ and tetrachloridozincate

被引：6

作者：

Lin, Tai ^{[1
]}

Gasperov, Vesna ^{[1
]}

Smith, Kate J. ^{[1
]}

Tong, Christine C. ^{[1
]}

Tasker, Peter A. ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 41期

基金：

英国工程与自然科学研究理事会;

关键词：

SOLVENT-EXTRACTION; ION-PAIR; M-X; TRANSPORT; MOLECULES; CHEMISTRY; BINDING;

D O I：

10.1039/c0dt00577k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Combining cation-and anion-binding functionalities in a salen-type extractant leads to multiple loading of ZnCl2. Zn(II) cations are bound by the salen N2O22- donor set, and chlorozincate anions are associated with protonated pendant amine groups.

引用

页码：9760 / 9762

页数：3

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