Double loading of ZnCl2 by polytopic ligands which co-extract Zn2+ and tetrachloridozincate

被引：6
作者：
Lin, Tai [1 ]
Gasperov, Vesna [1 ]
Smith, Kate J. [1 ]
Tong, Christine C. [1 ]
Tasker, Peter A. [1 ]
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 41期
基金：
英国工程与自然科学研究理事会;
关键词：
SOLVENT-EXTRACTION; ION-PAIR; M-X; TRANSPORT; MOLECULES; CHEMISTRY; BINDING;
D O I：
10.1039/c0dt00577k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Combining cation-and anion-binding functionalities in a salen-type extractant leads to multiple loading of ZnCl2. Zn(II) cations are bound by the salen N2O22- donor set, and chlorozincate anions are associated with protonated pendant amine groups.
引用
收藏
页码：9760 / 9762
页数：3
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