In-situ As-P exchange monitoring in metal-organic vapor phase epitaxy of InGaAs/InP heterostructure by spectroscopic and kinetic ellipsometry

被引:30
作者
Sudo, S [1 ]
Nakano, Y [1 ]
Sugiyama, M [1 ]
Shimogaki, Y [1 ]
Komiyama, H [1 ]
Tada, K [1 ]
机构
[1] Univ Tokyo, Dept Elect Engn, Sch Engn, Bunkyo Ku, Tokyo 113, Japan
关键词
spectroscopic ellipsometry; kinetic ellipsometry; MOVPE; in-situ monitoring; arsenic-phosphorus exchange; organic group V precursors;
D O I
10.1016/S0040-6090(97)00894-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In InGaAs/InP heterostructures, interdiffusion of arsenic and phosphorus at the hetero-interfaces during epitaxial growth degrades the interface abruptness. This is a serious problem when a very thin InGaAs/InP quantum well is required. In this paper, spectroscopic and kinetic ellipsometry are used to monitor the As-P exchange in-situ in metal-organic vapor phase epitaxy (MOVPE) with TBAs and TBP as the group V precursors. As a result, it is found that the monitoring of As-P exchange is possible by kinetic ellipsometry and that useful information for improving the gas switching sequence is acquired from such observations. Information from this in-situ kinetic ellipsometry has been confirmed to agree well with ex-situ photoluminescence and transmission electron microscope (TEM) observations. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:604 / 608
页数:5
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