Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

被引:23
作者
Cuesta, Luciano
Tomat, Elisa
Lynch, Vincent M.
Sessler, Jonathan L. [1 ]
机构
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
基金
美国国家科学基金会;
关键词
D O I
10.1039/b807126h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an eta(2)-fashion.
引用
收藏
页码:3744 / 3746
页数:3
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