XPS and Magnetic Properties of CoFe2O4 Nanoparticles Synthesized by a Polyacrylamide Gel Route

Cobalt ferrite CoFe2O4 nanoparticles were prepared via a polyacrylamide gel route and were characterized by XRD, SEM, XPS and VSM. It is demonstrated that the sample (designated SI) prepared without using the cross-linking agent bis-acrylamide has an average grain size of 45 nm, while the sample (designated S2) prepared by introducing an amount of bis-acrylamide which is about 1/5 times the amount of acrylamide has an average grain size of 23 nm. The two kinds of particles are shaped like spheres. The cation distribution is determined, from Co 2p(3/2) and Fe 2p(3/2) XPS spectra, to be (Co0.4Fe0.6)[Co0.6Fe1.4]O-4 for both the samples, where (Co0.4Fe0.6) and [Co0.6Fe1.4] represent cations in the tetrahedral and octahedral sites, respectively. Magnetic measurement reveals a saturation magnetization of 67.3 A.m(2).kg(-1) for sample S1 and 62.3 A.m(2).kg(-1) for sample S2, but a similar coercivity of about 87.5 kA.m(-1) for both the samples. [doi:10.2320/matertrans.M2012151]