Cs3Fe5O(OH)(AsO4)(5): A novel iron(III) arsenate containing four-, five- and six-coordinated iron atoms

被引：9

作者：

Wang, BL

Wang, SL

Lii, KH

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU,TAIWAN

[2] ACAD SINICA,INST CHEM,TAIPEI,TAIWAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 09期

关键词：

D O I：

10.1039/cc9960001061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel iron(III) arsenate is synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, which reveals a framework structure of vertex- and edge-sharing Fe-O polyhedra crosslinked by vertex-sharing AsO4 tetrahedra in a manner that generates tunnels and cavities occupied by Cs+ cations.

引用

页码：1061 / 1062

页数：2

共 13 条

[1] Syntheses and X-ray crystal structures of five- and six-coordinated iron(I) and iron(II) complexes with the same (eta(5)-C(5)Me(5))Fe(dppe) framework
Hamon, P
Toupet, L
Hamon, JR
Lapinte, C
ORGANOMETALLICS, 1996, 15 (01) : 10 - 12
[2] Rb-2[Ga-4(HPO4)(PO4)(4)]center dot 0.5H(2)O: A new gallium phosphate containing four-, five, and six-coordinated gallium atoms
Lii, KH
INORGANIC CHEMISTRY, 1996, 35 (25) : 7440 - &
[3] The novel arsenate Na3Al5O2(OH)2(AsO4)4: crystal structure and topological relations with minerals of the palermoite and carminite-attakolite families
Yakubovich, Olga V.
Kotelnikov, Alexey R.
Suk, Natalya I.
Chukanov, Nikita V.
EUROPEAN JOURNAL OF MINERALOGY, 2016, 28 (01) : 83 - 91
[4] CRYSTAL-STRUCTURES OF A CESIUM IRON(III) PHOSPHATE, CS3FE4(PO4)5, AND A CESIUM IRON(III) OXYPHOSPHATE, CS7FE7(PO4)8O2
ANDREWSALLEN, EM
ROBINSON, WR
JOURNAL OF SOLID STATE CHEMISTRY, 1988, 74 (01) : 88 - 97
[5] K3V2O3F4(IO3)3: a high-performance SHG crystal containing both five and six-coordinated V5+ cations
Chen, Jin
Hu, Chun-Li
Lin, Yi-Lin
Chen, Yan
Chen, Qian-Qian
Mao, Jiang-Gao
CHEMICAL SCIENCE, 2022, 13 (02) : 454 - 460
[6] Synthesis, structure, and magnetic properties of a novel pillared layered iron(III) arsenate, [4,4'-bpyH2]3[Fe9(H2O)6F3(HASO4)12(ASO4)2]•2H2O
Rao, Vandavasi K.
Green, Mark A.
Pati, Swapan K.
Natarajan, Srinivasan
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (44): : 12700 - 12706
[7] Cs5Mo8O24(OH)2AsO4u2H2O and Cs7Mo8O26 AsO4: Two: Novel Molybdenum(VI) Arsenates Containing Heteropolyanions [AsMo8-O30H2]5- and [AsMo8O30]7-
Hsu, K.-F.
Wang, S.-L.
Inorganic Chemistry, 36 (14):
[8] A new three-dimensional inorganic-organic hybrid fluorinated-iron(III) arsenate:: (C6H14N2)[Fe3(HASO4)2(AsO4)F4]0.5H2O.: Hydrothermal synthesis, crystal structure, and spectroscopic and magnetic properties
Bazán, B
Mesa, JL
Pizarro, JL
Goñi, A
Lezama, L
Arriortua, MI
Rojo, T
INORGANIC CHEMISTRY, 2001, 40 (22) : 5691 - +
[9] ,-Isomer of Open-Wells-Dawson Polyoxometalate Containing a Tetra-Iron(III) Hydroxide Cluster: [{Fe-4(H2O)(OH)(5)}(beta,beta-Si2W18O66)](9-)
Matsunaga, Satoshi
Miyamae, Eriko
Inoue, Yusuke
Nomiya, Kenji
INORGANICS, 2016, 4 (02)
[10] [H3N(CH2)(3)NH3]Fe2O(PO4)(2): A novel layered iron phosphate containing tetramers of FeO5 trigonal bipyramids
Lii, KH
Huang, YF
CHEMICAL COMMUNICATIONS, 1997, (14) : 1311 - 1312

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