Synthesis and properties of 1-(2-methyl-1-naphthyl)-2-(2-methyl-5-azidomethyl-3-thienyl)perfluorocyclopentene

被引：0

作者：

Tian, Z. Y. ^{[1
]}

Cui, S. Q. ^{[1
]}

Pu, S. Z. ^{[1
]}

机构：

[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China

来源：

3RD INTERNATIONAL CONFERENCE ON ADVANCED COMPOSITE MATERIALS AND MANUFACTURING ENGINEERING (CMME 2015) | 2015年

关键词：

DIARYLETHENES;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A photochromic diarylethene of 1-(2-Methyl-1-naphthyl)-2-(2-methyl-5-azidomethyl-3-thienyl) perfluorocyclopentene (1o) which bearing both naphthalene and thiophene moieties was synthesized and characterized. Its properties, including photochromic behavior, kinetics and fluorescent-switch properties have been investigated. Upon irradiation with UV light with the extended response time, the diarylethene underwent a ring opening reaction to produce closed forms and color change in solution. The results showed the compound exhibited good photochromism in hexane solution. The kinetic experiments showed that the cyclization and cycloreversion processes were zeroth and first order reaction, respectively. Moreover, 1o also exhibited obviously fluorescence switches along with the photochromism.

引用

页码：72 / 75

页数：4

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