EPR-investigations of radicals derived from diethyl lodomethylphosphonate in solid and liquid state

被引：5

作者：

Bialas, T ^{[1
]}

Szadowiak, A ^{[1
]}

Balczewski, P ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

HETEROATOM CHEMISTRY | 2004年 / 15卷 / 02期

关键词：

D O I：

10.1002/hc.10225

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A selective homolysis of the C-I bond in diethyl iodomethylphosphonate to give the diethoxyphosphorylmethyl radical (EtO)(2)P(O)CH2. was observed in EPR spectra upon gamma-irradiation and UV-vis photolysis. Analysis of stability of this radical was also investigated to show disappearance of EPR signals above 170-190 K. An attempt to observe this radical during the reaction with AIBN as an initiator failed. (C) 2004 Wiley Periodicals, Inc.

引用

页码：127 / 130

页数：4

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