Ring-opening polymerization of chloromethylthiirane with So(4)(2-)/TiO2/Nd3+ as initiator

被引：8

作者：

Shen, ZQ ^{[1
]}

Li, WS ^{[1
]}

Zhang, FY ^{[1
]}

Zhang, YF ^{[1
]}

Shen, LF ^{[1
]}

Yuan, HZ ^{[1
]}

机构：

[1] ACAD SINICA,WUHAN INST PHYS,STATE KEY LAB MAGNET RESONANCE & ATOM & MOL PHYS,WUHAN 430071,PEOPLES R CHINA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 09期

关键词：

D O I：

10.1002/marc.1997.030180903

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new type of solid superacid (SO42-/TiO2/Nd3+) was used for the ring-opening polymerization of chloromethylthiirane (CMT). TiO2 . H2O immersed in a sulfuric acid solution containing Nd3+ ions and calcined at 600 degrees C gave the solid superacid for initiating the polymerization of CMT. The effects of polymerization temperature and amount of the initiator on the CMT polymerization were studied. Poly(CMT) obtained has higher molecular weight ((M) over bar(W) = 52000) than ever reported.

引用

页码：769 / 773

页数：5

共 7 条

[1]

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