Catalytic Conversion of Chitosan to 5-Hydroxymethylfurfural Under Low Temperature Hydrothermal Process

被引：41

作者：

Lee, Sang-Bum ^{[1
]}

Jeong, Gwi-Taek ^{[1
]}

机构：

[1] Pukyong Natl Univ, Dept Biotechnol, Busan 608737, South Korea

来源：

APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY | 2015年 / 176卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

Green chemistry; Chitosan; 5-Hydroxymethylfurfural; Low temperature hydrothermal process; LEVULINIC ACID; CHITIN; BIOMASS;

D O I：

10.1007/s12010-015-1636-9

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

In this work, the catalytic conversion of natural polymer chitosan to 5-HMF under low temperature hydrothermal condition was investigated. The highest 5-HMF yield of 12.1 wt% was obtained under the following conditions: 174 degrees C reaction temperature, 2.2 % catalyst amount, and 36.9 min reaction time. In the effect of combined severity, the 5-HMF production linearly increased to the combined severity factor of 3.07. By the way, higher combined severity factor can cause the over-degradation of 5-HMF. From this result, chitosan showed significant potential as a feedstock for the production of platform chemicals such as 5-HMF.

引用

页码：1151 / 1161

页数：11

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