Bioleaching of indium from discarded liquid crystal displays

被引:65
作者
Jowkar, Mohammad Javad [1 ]
Bahaloo-Horeh, Nazanin [1 ]
Mousavi, Seyyed Mohammad [1 ]
Pourhossein, Fatemeh [1 ]
机构
[1] Tarbiat Modares Univ, Chem Engn Dept, Biotechnol Grp, Tehran, Iran
关键词
Bioleaching; Discarded LCDs; Indium recovery; Acidithiobacillus thiooxidans; Optimization; Kinetics; RESPONSE-SURFACE METHODOLOGY; BUBBLE-COLUMN BIOREACTOR; ACIDITHIOBACILLUS-FERROOXIDANS; HEAVY-METALS; ASPERGILLUS-NIGER; STATISTICAL EVALUATION; PROCESS OPTIMIZATION; SOLVENT-EXTRACTION; VALUABLE METALS; LCD PANELS;
D O I
10.1016/j.jclepro.2018.01.136
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The present study is the first report on the bioleaching of indium (In) from discarded liquid crystal displays (LCDs) using adapted Acidithiobacillus thiooxidans. The adaptation of bacteria to the LCDs powder began with 1% (w/v) and continued up to 4% (w/v). Response surface methodology (RSM) was used to evaluate the effects of initial pH, pulp density, and initial sulfur concentration and optimize their values in order to maximize In and Sr recovery. Under optimum conditions of an initial pH of 2.6, pulp density of 1.6% (w/v) and initial sulfur concentration of 8.6 (g/l), 100% of In and 10% of Sr were recovered. The rate-controlling step in this process was determined using the shrinking core model, which suggests that both diffusion and chemical reaction play an important role in the overall bioleaching process. Scanning electron microscopy (SEM) analysis demonstrated the effectiveness of bacterial activity in bioleaching. In addition, the results confirmed that bioleaching was more effective than chemical leaching. The bioleaching from discarded LCDs by A. thiooxidans is a promising technology that can decrease the environmental hazard of this waste. The bioleaching results of present study supplied a method for large-scale industrial purposes. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:417 / 429
页数:13
相关论文
共 50 条
[1]   Response surface methodology (RSM) analysis of organic acid production for Kaolin beneficiation by Aspergillus niger [J].
Aghaie, E. ;
Pazouki, M. ;
Hosseini, M. R. ;
Ranjbar, M. ;
Ghavipanjeh, F. .
CHEMICAL ENGINEERING JOURNAL, 2009, 147 (2-3) :245-251
[2]   Process modeling and analysis of biological nutrients removal in an integrated RBC-AS system using response surface methodology [J].
Akhbari, A. ;
Zinatizadeh, A. A. L. ;
Mohammadi, P. ;
Irandoust, M. ;
Mansouri, Y. .
CHEMICAL ENGINEERING JOURNAL, 2011, 168 (01) :269-279
[3]   Bioleaching kinetics of a spent refinery catalyst using Aspergillus niger at optimal conditions [J].
Amiri, F. ;
Mousavi, S. M. ;
Yaghmaei, S. ;
Barati, M. .
BIOCHEMICAL ENGINEERING JOURNAL, 2012, 67 :208-217
[4]   Multi-objective optimization of heavy metals bioleaching from discarded mobile phone PCBs: Simultaneous Cu and Ni recovery using Acidithiobacillus ferrooxidans [J].
Arshadi, M. ;
Mousavi, S. M. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2015, 147 :210-219
[5]   Simultaneous recovery of Ni and Cu from computer-printed circuit boards using bioleaching: Statistical evaluation and optimization [J].
Arshadi, M. ;
Mousavi, S. M. .
BIORESOURCE TECHNOLOGY, 2014, 174 :233-242
[6]   Enhanced recovery of valuable metals from spent lithium-ion batteries through optimization of organic acids produced by Aspergillus niger [J].
Bahaloo-Horeh, Nazanin ;
Mousavi, Seyyed Mohammad .
WASTE MANAGEMENT, 2017, 60 :666-679
[7]   Bioleaching of heavy metals from spent household batteries using Acidithiobacillus ferrooxidans: Statistical evaluation and optimization [J].
Bajestani, M. Ijadi ;
Mousavi, S. M. ;
Shojaosadati, S. A. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2014, 132 :309-316
[8]  
Bald C. P., 2015, GLOBAL E WASTE MONIT
[9]   Column bioleaching copper and its kinetics of waste printed circuit boards (WPCBs) by Acidithiobacillus ferrooxidans [J].
Chen, Shu ;
Yang, Yuankun ;
Liu, Congqiang ;
Dong, Faqin ;
Liu, Bijun .
CHEMOSPHERE, 2015, 141 :162-168
[10]   Growth in sulfidic mineral environments: metal resistance mechanisms in acidophilic micro-organisms [J].
Dopson, M ;
Baker-Austin, C ;
Koppineedi, PR ;
Bond, PL .
MICROBIOLOGY-SGM, 2003, 149 :1959-1970