Exploring a metalloligand for construction of an oxamato-based metal-organic framework

被引：0

作者：

Navarro-Alapont, Javier ^{[1
]}

Armentano, Donatella ^{[2
]}

Pardo, Emilio ^{[1
]}

Ferrando-Soria, Jesus ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol ICMol, Valencia 46980, Spain

[2] Univ Calabria, Dipartimento Chim & Tecnol Chim, Consenza, Italy

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2022年 / 75卷 / 17-18期

基金：

欧洲研究理事会;

关键词：

Metal organic frameworks; metalloligand design strategy; X-ray crystallography;

D O I：

10.1080/00958972.2022.2125303

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the two-step synthesis of a heterobimetallic oxamato-based metal-organic framework (MOF). First, we prepared an oxamato functionalized carbazole-based dinuclear copper(II) complex, K-4{Cu-2(carbox)(2)]}center dot 8H(2)O, where the carbozale linkers exhibited an uncommon substitution pattern, carbox = N,N'-1,6-carbazolebis(oxamate). Then, this building block was used as a metalloligand toward manganese(II) metal ions to assemble a neutral three-dimensional (3 D) MOF with formula [Mn2Cu2(carbox)(2)(H2O)(4)]center dot 6CH(3)OH center dot 2H(2)O (1) and single-crystal X-ray diffraction determined the structure. The resulting network constitutes one of the few examples of oxamato-based 3 D MOF.

引用

页码：2413 / 2423

页数：11

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