The potential of d6non-noble metal NHC catalysts for carbon dioxide hydrogenation: group and row effects

被引：18

作者：

Jing, Yaru ^{[1
]}

Ye, Zongren ^{[2
]}

Su, Jiaqi ^{[1
]}

Feng, Yishun ^{[2
]}

Qu, Ling-Bo ^{[3
]}

Liu, Yan ^{[1
]}

Ke, Zhuofeng ^{[2
]}

机构：

[1] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China

[2] Sun Yat Sen Univ, PCFM Lab, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China

[3] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2020年 / 10卷 / 16期

关键词：

LOW-PRESSURE HYDROGENATION; DEFINED IRON CATALYST; CO2; HYDROGENATION; FORMIC-ACID; COBALT; COMPLEXES; FORMATE; RHODIUM; REACTIVITY; REDUCTION;

D O I：

10.1039/d0cy01125h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of d(6)non-noble transition metal complexes were designed and studied computationally for the hydrogenation of CO(2)to formic acid. Catalysts with a metal of weak electronegativity and low oxidation state show improved potentials. Group VIB catalysts are predicted to be promising candidates, although less attention has been paid so far.

引用

页码：5443 / 5447

页数：5

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