Electrocatalytic Performances of Pure and Mixed Hexacyanoferrates of Cu and Pd for the Reduction of Hydrogen Peroxide

被引：15
作者：
Guadagnini, Lorella [1 ,2 ]
Giorgetti, Marco [1 ,2 ]
Tarterini, Fabrizio [2 ,3 ]
Tonelli, Domenica [1 ,2 ]
机构：
[1] Univ Bologna, Dipartimento Chim Fis & Inorgan, I-40136 Bologna, Italy
[2] UdR Bologna, INSTM, Bologna, Italy
[3] Dipartimento Sci Metalh Elettrochim & Tecn Chim, I-40136 Bologna, Italy
来源：
ELECTROANALYSIS | 2010年 / 22卷 / 15期
关键词：
Mixed metal hexacyanoferrates; Hydrogen peroxide; Electrocatalysis; Modified electrode; Copper; PRUSSIAN BLUE ANALOG; PALLADIUM HEXACYANOFERRATE; COPPER HEXACYANOFERRATE; ELECTROCHEMICAL PREPARATION; OPERATIONAL STABILITY; ALUMINUM ELECTRODE; COBALT HEXACYANOFERRATE; THIN-FILMS; BIOSENSORS; OXIDATION;
D O I：
10.1002/elan.200900569
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A study on the performances of mixed hexacyanoferrates of Cu and Pd (CuPdHCFs), potentiodynamically grown on glassy carbon surfaces. was earned out Morphological (SEM-EDX analysis) and electrochemical characterizations were pet formed, and the electrocatalytic ability of films with various compositions was tested by chronoamperometry CuPdHCFs were found to display good electrocatalytic performances. with a maximum sensitivity of 45 3 mA M-1 cm(-2) at 00 V vs SCE (depending on the Cu and Pd ration), against the value of 9 I mA M-1 cm(-2) obtained with pure copper hexacyanoferrate (CuHCF) Additionally, mixed hexacyanoferrates showed a higher pH and operational stability The key role of Cu in Cu-based hexacyanoferrates was investigated and highlighted
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页码：1695 / 1701
页数：7
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