Furanyl Alcohols as Alkylating Reagents in Friedel-Crafts Reaction of Arenes

被引：8

作者：

Iesce, Maria Rosaria ^{[1
]}

Sferruzza, Rosalia ^{[1
]}

Cermola, Flavio ^{[1
]}

DellaGreca, Marina ^{[1
]}

机构：

[1] Univ Naples Federico II, Complesso Univ Monte S Angelo, Dept Chem Sci, Via Cintia 4, IT-80126 Naples, Italy

来源：

HELVETICA CHIMICA ACTA | 2016年 / 99卷 / 04期

关键词：

Friedel-Crafts alkylation; Furan; Triflic anhydride; Triphenylphosphine oxide; Lignans; CARBOXYLIC-ACIDS; AROMATIC-COMPOUNDS; ACYLATION; ANHYDRIDE; ESTERS;

D O I：

10.1002/hlca.201500196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Furanyl alcohols react with arenes by a variant of the Friedel-Crafts reaction to give benzyl furans with fairly satisfying yields. The reaction is mediated by Tf2O and occurs with reduced times in the presence of Ph3PO. Some prepared compounds exhibit a lignan-like backbone.

引用

收藏

页码：296 / 301

页数：6

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