Palladium-catalyzed cyclization of alkenyl β-keto esters in the presence of chlorotrimethylsilane

被引：51

作者：

Pei, T ^{[1
]}

Widenhoefer, RA ^{[1
]}

机构：

[1] Duke Univ, Paul M Gross Chem Lab, Durham, NC 27708 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b111644d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

PdCl2(CH3CN)(2) catalyzed the cyclization of alkenyl beta-keto esters in the presence of a stoichiometric amount of SiMe3Cl to form 2-carboalkoxycyclohexanones in good yield with excellent regioselectivity.

引用

页码：650 / 651

页数：2

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