Mechanistic and kinetic investigation of liquid-liquid phase transfer catalyzed oxidation of benzyl chloride to benzaldehyde

被引：42

作者：

Yadav, GD

Haldavanekar, BV

机构：

[1] Chemical Engineering Division, Univ. Dept. of Chemical Technology, University of Bombay, Matunga

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 01期

关键词：

D O I：

10.1021/jp961678x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics and mechanism of liquid-liquid phase transfer catalyzed oxidation of benzyl chloride with chromate salts is investigated in great detail in a systematic way to throw light on the selectivity of the reaction to benzaldehyde. This system presents a complex case of consecutive and parallel reactions in which benzyl alcohol is formed as an intermediate which is further oxidized to benzaldehyde. The results are novel, and the experimental data fit the theoretical model very well.

引用

页码：36 / 48

页数：13

共 25 条

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Cainelli G., 1984, CHROMIUM OXIDATIONS

[2] CHROMATE ION AS A SYNTHETICALLY USEFUL NUCLEOPHILE - NOVEL SYNTHESIS OF ALDEHYDES FROM ALKYL-HALIDES [J].