Structure-Property Investigations of Substituted Triarylamines and Their Applications as Fluorescent pH Sensors

被引：23

作者：

Hu, Binbin ^{[1
]}

Chen, Xiaopeng ^{[1
]}

Wang, Yifei ^{[1
]}

Lu, Ping ^{[1
]}

Wang, Yanguang ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2013年 / 8卷 / 06期

关键词：

fluorescence; sensors; solvent effects; structureproperty relationship; triphenylamines; FIELD-EFFECT TRANSISTORS; INTRAMOLECULAR CHARGE-TRANSFER; SENSITIZED SOLAR-CELLS; LIGHT-EMITTING-DIODES; THIN-FILM TRANSISTORS; CONJUGATED POLYMERS; ELECTROLUMINESCENT DEVICES; 2-PHOTON ABSORPTION; INDUCED EMISSION; DYE;

D O I：

10.1002/asia.201300028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fourteen triphenylamine derivatives functionalized with fluorophenyl, methoxyphenyl, and pyridinyl groups as respective donors and acceptors were synthesized and characterized. Their photophysical properties were systematically investigated in various solvents with different polarities. The solvent-dependent Stokes shifts of these compounds were observed and analyzed by the LippertMataga equation. The synthesized compounds, especially tris(4-(pyridin-4-yl)phenyl) amine, presented pH-dependent absorptions and emissions, indicating that these compounds might be used as pH sensors.

引用

页码：1144 / 1151

页数：8

共 60 条

[1]

[Anonymous], 2004, ANGEW CHEM INT ED, V43, P1694

[2]

[Anonymous], 1998, ANGEW CHEM INT ED, V37, P402

[3] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[4] Investigation of two-photon absorption properties in branched alkene and alkyne chromophores [J].

Bhaskar, Ajit ;

Ramakrishna, Guda ;

Lu, Zhikuan ;

Twieg, Robert ;

Hales, Joel M. ;

Hagan, David J. ;

Van Stryland, Eric ;

Goodson, Theodore, III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (36) :11840-11849

[5] Trinaphthylamines as Robust Organic Materials for Two-Photon-Induced Fluorescence [J].

Bordeau, Guillaume ;

Lartia, Remy ;

Metge, Germain ;

Fiorini-Debuisschert, Celine ;

Charra, Fabrice ;

Teulade-Fichou, Marie-Paule .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (50) :16836-+

[6] High-Performance Organic Field-Effect Transistors [J].

Braga, Daniele ;

Horowitz, Gilles .

ADVANCED MATERIALS, 2009, 21 (14-15) :1473-1486

[7] Conjugated polymer photovoltaic cells [J].

Coakley, KM ;

McGehee, MD .

CHEMISTRY OF MATERIALS, 2004, 16 (23) :4533-4542

[8] Star-shaped perylene-oligothiophene-triphenylamine hybrid systems for photovoltaic applications [J].

Cremer, J ;

Bäuerle, P .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (09) :874-884

[9]

Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO

[10]

2-9

← 1 2 3 4 5 6 →