End group cross-linked 2-(dimethylamino) ethylmethacrylate based anion exchange membrane for electrodialysis

被引：25

作者：

Chakrabarty, Tina ^{[1
]}

Prakash, S. ^{[1
]}

Shahi, Vinod K. ^{[1
]}

机构：

[1] CSIR, Electromembrane Proc Div, Cent Salt & Marine Chem Res Inst, Bhavnagar 364002, Gujarat, India

来源：

JOURNAL OF MEMBRANE SCIENCE | 2013年 / 428卷

关键词：

Chlorine tolerant membrane; Cross-linked membranes; Fuel cells; Anion-exchange membrane; Electrodialysis; CONDUCTIVITY; POLYMERIZATION; COPOLYMERS; DIFFUSION; STATE; WATER;

D O I：

10.1016/j.memsci.2012.11.002

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Anion exchange membranes (AEMs) emerged as an important material for alkaline fuel cells, and electrochemical applications. Herein, we are reporting synthesis of poly (vinyltrimethoxysilane-co-2-(dimethylamino) ethylmethacrylate) copolymer (VTMS-co-DMAEMA) by eco-friendly method for the preparation of AEM. Obtained membranes were cross-linked via formal reaction and quaternized by methyl iodide. Developed AEM showed good stabilities (oxidative, chlorine, dimensional, mechanical and thermal) and electrochemical properties. These membranes were designed to possess all the required properties of highly anion conductive membrane such as reasonable water uptake, good ion-exchange capacity (2.92 mequiv g(-1)), high permselectivity (0.90), along with reasonableconductivity (6.45 x 10(-2) S cm(-1)). The excellent electro-transport property of AEM-0.08 for practical anion separation was concluded from i-v studies. Electrodialytic performance of the AEM-0.08 membrane revealed its suitability for applications in electromembrane processes. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：86 / 94

页数：9

共 43 条

[31] Surface-initiated atom transfer radical polymerization: A new method for preparation of polymeric membrane adsorbers [J].

Singh, Nripen ;

Wang, Jun ;

Ulbricht, Mathias ;

Wickramasinghe, S. Ranil ;

Husson, Scott M. .

JOURNAL OF MEMBRANE SCIENCE, 2008, 309 (1-2) :64-72

[32] A green method for the preparation of highly stable organic-inorganic hybrid anion-exchange membranes in aqueous media for electrochemical processes [J].

Singh, Shalini ;

Jasti, Amaranadh ;

Kumar, Mahendra ;

Shahi, Vinod K. .

POLYMER CHEMISTRY, 2010, 1 (08) :1302-1312

[33] Electrolyte diffusive flux determination through a highly selective cation exchange membrane [J].

Tourreuil, V ;

Dammak, L ;

Bulvestre, G ;

Auclair, B .

NEW JOURNAL OF CHEMISTRY, 1999, 23 (02) :173-178

[34] Highly charged and stable cross-linked 4,4′-bis(4-aminophenoxy) biphenyl-3,3′-disulfonic acid (BAPBDS)-sulfonated poly(ether sulfone) polymer electrolyte membranes impervious to methanol [J].

Tripathi, Bijay P. ;

Chakrabarty, Tina ;

Shahi, Vinod K. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (37) :8036-8044

[35] Functionalized Organic-Inorganic Nanostructured N-p-Carboxy Benzyl Chitosan-Silica-PVA Hybrid Polyelectrolyte Complex as Proton Exchange Membrane for DMFC Applications [J].

Tripathi, Bijay P. ;

Shahi, Vinod K. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (49) :15678-15690

[36] 3-[[3-(Triethoxysilyl)propyl]amino]propane-1-sulfonic Acid-Poly(vinyl alcohol) Cross-Linked Zwitterionic Polymer Electrolyte Membranes for Direct Methanol Fuel Cell Applications [J].

Tripathi, Bijay P. ;

Shahi, Vinod K. .

ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (05) :1002-1012

[37] Novel anion-exchange organic-inorganic hybrid membranes prepared through sol-gel reaction and UV/thermal curing [J].

Wu, Cuiming ;

Wu, Yonghui ;

Xu, Tongwen ;

Fu, Yanxun .

JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (03) :1865-1871

[38] Novel anion exchange membrane based on copolymer of methyl methacrylate, vinylbenzyl chloride and ethyl acrylate for alkaline fuel cells [J].

Xu, Hankun ;

Fang, Jun ;

Guo, Mingli ;

Lu, Xiaohuan ;

Wei, Xiaolan ;

Tu, Song .

JOURNAL OF MEMBRANE SCIENCE, 2010, 354 (1-2) :206-211

[39] Preparation of a novel hollow-fiber anion-exchange membrane and its preliminary performance in diffusion dialysis [J].

Xu, Tongwen ;

Liu, Zhaoming ;

Huang, Chuanhui ;

Wu, Yonghui ;

Wu, Liang ;

Yang, Weihua .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (16) :6204-6210

[40] Study of ionic transport properties of alkaline poly(vinyl) alcohol-based polymer electrolytes [J].

Yang, CC ;

Lin, SJ ;

Wu, GM .

MATERIALS CHEMISTRY AND PHYSICS, 2005, 92 (01) :251-255

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