Kinetics and mechanism of iridium(III) catalyzed oxidation of some cyclic alcohols by potassium bromate in acidic medium

被引：0

作者：

Srivastava, S ^{[1
]}

Sharma, RK ^{[1
]}

Singh, S ^{[1
]}

机构：

[1] Feroze Gandhi Postgrad Coll, Chem Labs, Rae Bareli 229001, Uttar Pradesh, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2006年 / 83卷 / 03期

关键词：

iridium(III) catalysis; cyclic alcohols; potassium bromate; kinetics and mechanism;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic study of iridium(III) catalyzed oxidation of cyclopentanol, cyclohexanol and cycloheptanol by potassium bromate in acidic solution have been made in the presence of mercuric acetate. The reaction exhibits first order with respect to oxidant, zero-order with respect to substrates. Rate is not affected by hydrogen ion concentration, however Cl- enhances the rate. A plausible mechanism based on these observations has been suggested.

引用

页码：282 / 287

页数：6