Ternary phthalocyanato Hf(IV) and Zr(IV) polyoxometalate complexes

被引：6

作者：

Radivojevic, Ivana ^{[1
,2
]}

Ithisuphalap, Kemakorn ^{[1
,2
]}

Burton-Pye, Benjamin P. ^{[1
,2
]}

Saleh, Raihan ^{[1
,2
]}

Francesconi, Lynn C. ^{[1
,2
]}

Drain, Charles Michael ^{[1
,2
,3
]}

机构：

[1] CUNY Hunter Coll, New York, NY 10065 USA

[2] CUNY, Grad Ctr, New York, NY 10065 USA

[3] Rockefeller Univ, New York, NY 10065 USA

来源：

RSC ADVANCES | 2013年 / 3卷 / 07期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

SPECTRAL PROPERTIES; SELF-ORGANIZATION; PORPHYRIN; ZIRCONIUM(IV); FILMS; CHEMISTRY;

D O I：

10.1039/c2ra22903j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ternary phthalocyanine-metal-polyoxometalate (Pc-M-POM) complexes were synthesized and characterized. Group (IV) Hf or Zr ions reside outside the plane of the macrocycle and are coordinated to both the phthalocyanine and the lacunary polyoxometalate. The metal ions mediate the electronic communication between the Pc and the POM.

引用

页码：2174 / 2177

页数：4

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