Hydrothermal Synthesis, Structure, and Electrochemical Properties of a Three-dimensional Vanadium-Nickel Phosphate (C2H10N2)4[H2Ni(H2O)2(VO)8(OH)4(PO4)8]•H2O

被引：2
作者：
Yin, Fan-Wen [1 ]
Peng, Cheng-Dong [1 ]
Li, Ya-Si [1 ]
Zhuang, Ting-Ting [1 ]
Zeng, Qing-Xin [1 ]
Yuan, Zhan-Hui [2 ]
机构：
[1] Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Fuzhou Kuncai Fine Chem Co Ltd, Fuzhou 350314, Fujian, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 3-4期
关键词：
Hydrothermal synthesis; Vanadium; Nickel; Phosphates; Electrochemical properties; Electron sponge; CHEMISTRY; PHASES;
D O I：
10.1002/zaac.201200449
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The three-dimensional vanadium-nickel phosphate (C2H10N2)4[H2Ni(H2O)2(VO)8(OH)4(PO4)8]center dot H2O (1) was prepared by hydrothermal methods and its structure and electrochemical properties were characterized. The compound crystallizes in the monoclinic system with the space group P21/n and cell parameters a = 14.392(3) angstrom, b = 10.122(2) angstrom, c = 18.305(4) angstrom, = 90.34(3)degrees, V = 2666.7(9) angstrom 3, Z = 2. The structure consists of macroanionic VNiP layers constructed from VO5 square pyramids, NiO6 octahedra, and PO43 tetrahedral groups. The layers are further connected into a 3D infinite structure through the NiO6 octahedra and there are organic species protonated ethanediamine molecules and water molecules located, which make the structure more stable. Its electron sponge behavior was revealed via electrochemical tests.
引用
收藏
页码：543 / 547
页数：5
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