Conversion of highly concentrated cellulose to 1,2-propanediol and ethylene glycol over highly efficient CuCr catalysts

被引：106

作者：

Xiao, Zihui ^{[1
]}

Jin, Shaohua ^{[1
]}

Pang, Min ^{[1
]}

Liang, Changhai ^{[1
]}

机构：

[1] Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116012, Peoples R China

来源：

GREEN CHEMISTRY | 2013年 / 15卷 / 04期

基金：

中国国家自然科学基金;

关键词：

BIMETALLIC CATALYSTS; GLYCEROL; HYDROGENOLYSIS; RU; POLYOLS;

D O I：

10.1039/c3gc40134k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct hydrogenolysis of highly concentrated cellulose (up to 15 wt%) into 1,2-propanediol and ethylene glycol without the formation of coke-like precipitates could be performed over CuCr catalysts. Addition of Ca(OH)(2) results in a significant increase in the EG yield.

引用

页码：891 / 895

页数：5

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