Inhibition Effect and Adsorption Behavior of New Azodye Derivatives on Corrosion of Carbon Steel in Acid Medium

被引：27

作者：

El-Haddad, M. N. ^{[1
]}

Fouda, A. S. ^{[1
]}

机构：

[1] Mansoura Univ, Fac Sci, Dept Chem, Mansoura 35516, Egypt

来源：

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2013年 / 34卷 / 10期

关键词：

Adsorption mechanism; carbon steel; inhibition efficiency; quantum chemical calculation; ELECTROCHEMICAL FREQUENCY-MODULATION; SCHIFF-BASE COMPOUNDS; MILD-STEEL; HCL SOLUTIONS; NITROGEN; SURFACE; IRON;

D O I：

10.1080/01932691.2012.735922

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The inhibition effects of synthesized azodye derivatives on carbon steel corrosion in 2.0M HCl were studied using weight loss, potentiodynamic polarization, and electrochemical frequency modulation (EFM) techniques. Potentiodynamic polarization measurements show that azodye derivatives are mixed-type inhibitors. EFM can be used as a rapid and non destructive technique for corrosion rate measurements without prior knowledge of Tafel constants. The results obtained from weight loss, potentiodynamic polarization and EFM measurements were in good agreement. Adsorption of these inhibitors on the surface on carbon steel follows the Langmuir adsorption isotherm. The surface of carbon steel examined using UV-vis reflectance spectroscopy. Quantum chemical calculations have been performed and several quantum chemical parameters were calculated and correlated with the corresponding inhibition efficiencies.

引用

页码：1471 / 1480

页数：10

共 41 条

[1] Synthesis of some 4-arylazo-3-hydroxythiophene disperse dyes for dyeing polyester fabrics
Abdel-Latif, Ehab
Amer, Fathy A.
[J]. MONATSHEFTE FUR CHEMIE, 2008, 139 (05): : 561 - 567
[2] The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid - Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies
Amin, Mohammed A.
El-Rehim, Sayed S. Abd
El-Sherbini, E. E. F.
Bayoumi, Rady S.
[J]. ELECTROCHIMICA ACTA, 2007, 52 (11) : 3588 - 3600
[3] Electrochemical frequency modulation and inductively coupled plasma atomic emission spectroscopy methods for monitoring corrosion rates and inhibition of low alloy steel corrosion in HCl solutions and a test for validity of the Tafel extrapolation method
Amin, Mohammed A.
El Rehim, Sayed S. Abd
Abdel-Fatah, Hesham T. M.
[J]. CORROSION SCIENCE, 2009, 51 (04) : 882 - 894
[4] Apparao P. V., 2010, J CHEM SCI, V122, P639
[5] Corrosion and hydrogen permeation inhibition for mild steel in HCl by isomers of organic compounds
Babu, BR
Holze, R
[J]. BRITISH CORROSION JOURNAL, 2000, 35 (03): : 204 - 209
[6] CONTRIBUTION TO ADSORPTION OF AROMATIC-AMINES ON MILD-STEEL SURFACE FROM HCL SOLUTIONS BY IMPEDANCE, UV, AND RAMAN-SPECTROSCOPY
BANERJEE, G
MALHOTRA, SN
[J]. CORROSION, 1992, 48 (01) : 10 - 15
[7] The influence of some new 2,5-disubstituted 1,3,4-thiadiazoles on the corrosion behaviour of mild steel in 1 M HCl solution:: AC impedance study and theoretical approach
Bentiss, F.
Lebrini, M.
Lagrenee, M.
Traisnel, M.
Elfarouk, A.
Vezin, H.
[J]. ELECTROCHIMICA ACTA, 2007, 52 (24) : 6865 - 6872
[8] Effect of iodide ions on corrosion inhibition of mild steel by 3,5-bis(4-methylthiophenyl)-4H-1,2,4-triazole in sulfuric acid solution
Bentiss, F
Bouanis, M
Mernari, B
Traisnel, M
Lagrenee, M
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2002, 32 (06) : 671 - 678
[9] Electrochemical frequency modulation: A new electrochemical technique for online corrosion monitoring
Bosch, RW
Hubrecht, J
Bogaerts, WF
Syrett, BC
[J]. CORROSION, 2001, 57 (01) : 60 - 70
[10] Thiophene derivatives as effective inhibitors for the corrosion of steel in 0.5 M H2SO4
Bouklah, M
Hammouti, B
Benkaddour, M
Benhadda, T
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2005, 35 (11) : 1095 - 1101

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