New chiral polyfunctional cyclobutane derivatives from (-)-verbenone: possible surfactant behaviour

被引：3

作者：

Ospina, Jimena ^{[1
]}

Sorrenti, Alessandro ^{[1
]}

Illa, Ona ^{[1
]}

Pons, Ramon ^{[2
]}

Ortuno, Rosa M. ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Quim, Cerdanyola Del Valles 08193, Spain

[2] IQAC CSIC, Dept Tecnol Quim & Tensioactius, Inst Quim Avancada Catalunya, Barcelona 08034, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2013年 / 24卷 / 12期

关键词：

STEREOSELECTIVE-SYNTHESIS; ACID-DERIVATIVES; AMINO-ACIDS; HYDROGENATION; MICELLIZATION; CATALYST; ARGININE; SYSTEMS; SAXS;

D O I：

10.1016/j.tetasy.2013.05.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New enantiopure cyclobutane derivatives have been synthesized from a chiral precursor derived from (-)-verbenone. The cyclobutane moiety acts as a chiral platform to afford a gamma-amino acid function in a branched side-chain containing an additional stereogenic centre as well as additional C-6 or C-15-alkyl chains linked to the ring by means of an amine or an amide function. One of these compounds, obtained as a 1:2 mixture with its TFA salt has been investigated, suggesting behaviour as a good surfactant and its critical micellar concentration has been determined. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：713 / 718

页数：6

共 49 条

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