Imidazolium-based ionic liquids as efficient shape-regulating solvents for the synthesis of gold nanorods

被引：80

作者：

Ryu, Hyung Ju ^{[1
]}

Sanchez, Luz ^{[2
]}

Keul, Heidrun A. ^{[3
,4
]}

Raj, Aanchal ^{[1
]}

Bockstaller, Michael R. ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Mat Sci & Engn, Pittsburgh, PA 15213 USA

[2] CUNY Hunter Coll, Dept Phys & Astron, New York, NY 10021 USA

[3] Rhein Westfal TH Aachen, DWI, D-52056 Aachen, Germany

[4] Rhein Westfal TH Aachen, Inst Tech & Macromol Chem, D-52056 Aachen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 40期

基金：

美国国家科学基金会;

关键词：

crystal growth; gold; ionic liquids; nanorods; shape regulation;

D O I：

10.1002/anie.200802185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shape control: Gold nanorods are synthesized in high yields in the absence of shape-regulating agents in 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM] [ES]). A two-step seeded-growth process is used that capitalizes on the binding affinity of imidazolium cations to gold crystal facets, the stabilization of AuI in [EMIM][ES], and the reduction of particle growth rates that is facilitated by weak reducing agents. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7639 / 7643

页数：5

共 50 条

[1] Ionic Liquids as Size- and Shape-Regulating Solvents for the Synthesis of Cobalt Nanoparticles
Essig, Sarah
Behrens, Silke
CHEMIE INGENIEUR TECHNIK, 2015, 87 (12) : 1741 - 1747
[2] Imidazolium-based ionic liquids
Wang Zhongni
Wang Jieying
Si Youhua
Zhou Wu
PROGRESS IN CHEMISTRY, 2008, 20 (7-8) : 1057 - 1063
[3] Gold imidazolium-based ionic liquids, efficient catalysts for cycloisomerization of γ-acetylenic carboxylic acids
Neatu, Florentina
Parvulescu, Vasile I.
Michelet, Veronique
Genet, Jean-Pierre
Goguet, Alexandre
Hardacre, Christopher
NEW JOURNAL OF CHEMISTRY, 2009, 33 (01) : 102 - 106
[4] Dynamic wetting of imidazolium-based ionic liquids on gold and glass
Delcheva, I.
Beattie, D. A.
Ralston, J.
Krasowska, M.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (03) : 2084 - 2093
[5] Imidazolium-based chiral ionic liquids: synthesis and application
Suzuki, Yumiko
Wakatsuki, Junichiro
Tsubaki, Mariko
Sato, Masayuki
TETRAHEDRON, 2013, 69 (46) : 9690 - 9700
[6] Bicyclic imidazolium-based ionic liquids: synthesis and characterization
Kan, Huang-Chuan
Tseng, Ming-Chung
Chu, Yen-Ho
TETRAHEDRON, 2007, 63 (07) : 1644 - 1653
[7] Imidazolium-based ionic liquids as cellulose solvents: Mechanism and molecular insights
Rizvi, Sarmad
Gade, Hrushikesh M.
BIOMASS & BIOENERGY, 2025, 196
[8] Shape-controlled synthesis of silver crystals mediated by imidazolium-based ionic liquids
Kim, Tae Young
Yeon, Ji Hye
Kim, So Ra
Kim, Chul Young
Shim, Jong Pil
Suh, Kwang S.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (36) : 16138 - 16141
[9] The simulation of imidazolium-based ionic liquids
Hunt, PA
MOLECULAR SIMULATION, 2006, 32 (01) : 1 - 10
[10] Ionothermal synthesis of uranyl compounds in imidazolium-based ionic liquids
Wylie, Ernest M.
Peruski, Kathryn M.
Burns, Peter C.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246

← 1 2 3 4 5 →