Acceleration of calcite kinetics by abalone nacre proteins

被引:125
作者
Fu, G
Qiu, SR
Orme, CA
Morse, DE
De Yoreo, JJ
机构
[1] Lawrence Livermore Natl Lab, Dept Chem & Mat Sci, Livermore, CA 94551 USA
[2] Univ Calif Santa Barbara, Biomol Sci & Engn Grad Program, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Inst Collaborat Biotechnol, Santa Barbara, CA 93106 USA
关键词
D O I
10.1002/adma.200500633
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Abalone shell nacre proteins act as surfactants to promote ion attachment at calcite steps, causing acceleration of the molecular-scale kinetics of calcite crystal growth. The proteins modify the shape of growing calcite (see Figure) through step-specific interactions, even though the proteins are larger than the atomic-scale steps. Understanding of crystal-growth control by interactions with proteins may give better control of new crystalline materials.
引用
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页码:2678 / +
页数:7
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