Catalytic Carbanion Reactions: Formation and Reaction of Carbanions from Ester or Amide Equivalents Using Catalytic Amounts of Bases

被引：43

作者：

Kobayashi, Shu ^{[1
]}

Matsubara, Ryosuke

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, HFRE Div,ERATO Japan Sci Technol Agcy JST,Bunkyo, Tokyo 1130033, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 41期

关键词：

aldol reaction; amides; carbanions; imines; MANNICH-TYPE REACTIONS; ACID-DERIVATIVES; ASYMMETRIC ALDOL; COMPLEXES; MICHAEL; 1,4-ADDITION; AMINATION; ADDITIONS;

D O I：

10.1002/chem.200901515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe here carbanion reactions using catalytic amounts of bases. The carbanions formed are different from conventional carbanions in which stoichiometric amounts of bases are needed for the formation. Two types of reactions using such carbanions from amide (imido) and ester equivalents are discussed.

引用

页码：10694 / 10700

页数：7

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