Ni(II) complex of octasubstituted tetraphenylporphine as a stationary phase for gas chromatography

被引：8

作者：

Burmistrov, Vladimir A. ^{[1
]}

Semeikin, Alexander S. ^{[1
]}

Kuvshinov, Gregory V. ^{[1
]}

Aleksandriiskii, Victor V. ^{[1
,2
]}

Lubimova, Tatiana V. ^{[1
]}

Kuvshinova, Sofia A. ^{[1
]}

Koifman, Oscar I. ^{[1
,2
]}

机构：

[1] Ivanovo State Univ Chem & Technol, Res Inst Macroheterocycles, Ivanovo 153000, Russia

[2] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo 153045, Russia

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2017年 / 21卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

porphyrins; complexes; stationary phase; gas chromatography; selectivity; SOLID CHROMATOGRAPHY; ORGANIC-COMPOUNDS; PORPHYRIN; PHTHALOCYANINES;

D O I：

10.1142/S1088424617500110

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Ni(II) complex of 5,10,15,20-tetrakis[3', 5'-di(2''-methylbutyloxy) phenyl] porphine was synthesized and characterized by (HNMR)-H-1, UV-vis spectroscopy and MALDI-TOF mass-spectrometry. The stationary phase on the base of synthesized Ni(II) complex was used for chromatographic separation of isomeric methyl-and dimethylpyridines. The high structural selectivity of this sorbent was explained by giving the results of DFT calculation of pyridine derivatives axial complexes with porphyrin Ni(II) complexes.

引用

页码：103 / 109

页数：7

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